Activated carbon treatment of harmful gases

In order to provide reference and theoretical basis for the preparation and selection of activated carbon for the adsorption of dioxins, this paper carried out a study on the combined technology of activated carbon injection and double bag dust collector, the characteristics of activated carbon adsorption for dioxins and the influencing factors of activated carbon adsorption for dioxins.The adsorption and desorption isotherms of 13 kinds of commercial activated carbon were determined by low temperature nitrogen adsorption method, and the physical structures of activated carbon were calculated according to BET, T-Plot, BJH and DFT theory, and the iodine value and methylene blue value of 4 kinds of activated carbon were detected.activated carbon manufacturer
The physical structure characteristics of activated carbon were analyzed in detail to prepare for the subsequent experiment.
Using small activated carbon fixed bed adsorption gas phase dioxin test bench, a typical activated carbon adsorption dioxin factors affecting the experimental study, discusses the types of dioxin adsorption activated carbon and activated carbon fixed bed adsorption gas phase characteristics of dioxins, and discusses the adsorption temperature and adsorption time of activated carbon adsorption of dioxins.The results showed that the specific surface area and micropore volume of activated carbon had weak correlation with the adsorption efficiency of dioxins.
The mesopore volume of activated carbon is an important factor to determine the adsorption capacity of dioxins. The surface area of the pore size between 2 nm and 20nm plays a key role in the adsorption of dioxins.The higher the adsorption temperature, the lower the adsorption efficiency of activated carbon.The longer the adsorption time, the lower the adsorption efficiency of activated carbon.There is no selective adsorption of gaseous dioxins in activated carbon fixed By single factor experiment, the optimal conditions of carbon production were obtained as follows: pyrolysis temperature 600℃, activator concentration 4 mol · L', pyrolysis time 1.5h, solid-liquid ratio 1:2.5.Orthogonal experiment showed that the influence of each factor was as follows: pyrolysis temperatureIs the activator concentration Pyrolysis time >Solid-liquid ratio.(4) the main performance of PAC is basically equivalent to 8818 type activated carbon;coconut shell granular activated carbon
The concentrations of heavy metals in activated carbon leaching solution of sludge were all qualified.Compared with domestic and foreign research reports, the quality of PAC is in the middle level.(5) Compared with SAC, the specific surface area of PAC is larger, up to 636.8m2·g'. PAC is mainly mesoporous, but also contains some micropores. The adsorption/desorption isotherm shows that PAC is activated carbon with parallel wall slit pore structure.